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Proceedings Paper

Electrochemical and mirage investigations on films of Prussian blue and its analogs
Author(s): Vincent Plichon; M. Bardin; J. P. Delboulbe; C. Galland; B. Zaid
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Paper Abstract

Heavy-metal hexacyanoferrate stability during voltammetric cycling on the FeIII(CN)63-/FeII(CN)64- is explained by the nature of the ions entering or leaving the film. In contact with a KCl aqueous electrolyte, as many cycling can be performed as more K+ ions are intercalated in the lattice. This is concluded from the relation between the stability of the iron(III), indium(III), and copper(II) compounds, and the nature of the ions leaving or entering the film during a voltammetric cycle, as shown by the mirage technique.

Paper Details

Date Published: 25 November 1992
PDF: 8 pages
Proc. SPIE 1728, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XI: Chromogenics for Smart Windows, (25 November 1992); doi: 10.1117/12.130538
Show Author Affiliations
Vincent Plichon, ESPCI (France)
M. Bardin, ESPCI (France)
J. P. Delboulbe, ESPCI (France)
C. Galland, ESPCI (France)
B. Zaid, ESPCI (France)


Published in SPIE Proceedings Vol. 1728:
Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XI: Chromogenics for Smart Windows

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