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Journal of Nanophotonics

Designing nanostructured one-dimensional TiO2 nanotube and TiO2 nanoparticle multilayer composite film as photoanode in dye-sensitized solar cells to increase the charge collection efficiency
Author(s): Jeganathan Akilavasan; Maufick Al-Jassim; Jayasundera Bandara
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Paper Abstract

A photoanode consisting of hydrothermally synthesized TiO2 nanotubes (TNT) and TiO2 nanoparticles (TNP) was designed for efficient charge collection in dye-sensitized solar cells. TNT and TNP films were fabricated on a conductive glass substrate by using electrophoretic deposition and doctor-blade methods, respectively. The TNP, TNT, and TNT/TNP bi-layer electrodes exhibit solar cell efficiencies of 5.3, 7.4, and 9.2%, respectively. Solar cell performance results indicate a higher short-circuit current density (Jsc) for the TNT/TNP bi-layer electrode when compared to a TNT or TNP electrode alone. The open-circuit voltages (Voc) of TNT/TNP and TNT electrodes are comparable while the Voc of TNP electrode is inferior to that of the TNT/TNP electrode. Fill factors of TNT/TNP, TNT, and TNP electrodes also exhibit similar behaviors. The enhanced efficiency of the TNT/TNP bi-layer electrode is found to be mainly due to the enhancement of charge collection efficiency, which is confirmed by the charge transport parameters measured by electrochemical impedance spectroscopy (EIS). EIS analyses also revealed that the TNT/TNP incurs smaller charge transport resistances and longer electron life times when compared to those of TNT or TNP electrodes alone. It was demonstrated that the TNT/TNP bi-layer electrode can possess the advantages of both rapid electron transport rate and a high light scattering effect.

Paper Details

Date Published: 20 February 2015
PDF: 12 pages
J. Nanophoton. 9(1) 093091 doi: 10.1117/1.JNP.9.093091
Published in: Journal of Nanophotonics Volume 9, Issue 1
Show Author Affiliations
Jeganathan Akilavasan, Institute of Fundamental Studies (Sri Lanka)
Maufick Al-Jassim, National Renewable Energy Lab. (United States)
Jayasundera Bandara, Institute of Fundamental Studies (Sri Lanka)


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