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Journal of Nanophotonics

Blue cooperative upconversion and white light emission from Y2Si2O7:Yb3+ nanopowders due to 975-nm infrared excitation
Author(s): Gonul Eryurek; Hatun Cinkaya; Murat Erdem; Gokhan Bilir
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Paper Abstract

We report the luminescence properties of undoped and 10% Yb3+-doped Y2Si2O7 nanopowders under the infrared excitation of 975-nm laser diode. A broadband white light (WL) emission is observed in the undoped powder, and its intensity becomes stronger with increasing excitation power. A blue emission centered at ∼475  nm is observed below the excitation power of ∼2  W in the Yb3+-doped sample. The blue emission intensity dependence on the excitation power suggests that this emission is a two-photon absorption process known as the cooperative luminescence of Yb3+ ions. When the excitation power is increased above 2 W, a broadband “white” emission extending from blue into the near infrared appears while the blue cooperative emission band of Yb3+ ions disappears. The excitation power dependence of the WL intensity at 758 nm is due to a multiphoton process that may be attributed to the thermal radiation mechanism. The International Commission on Illumination coordinates (x,y) for the WL emission in the Yb3+-doped Y2Si2O7 nanocrystalline sample is found to be (0.4503, 0.3999) and (0.5035, 0.4096) for 2.005- and 3.68-W excitation powers, respectively. These values lie in the yellowish region and correspond to the color temperature value of 5030 K, with a color rendering index of 85.

Paper Details

Date Published: 26 May 2016
PDF: 9 pages
J. Nanophoton. 10(2) 026022 doi: 10.1117/1.JNP.10.026022
Published in: Journal of Nanophotonics Volume 10, Issue 2
Show Author Affiliations
Gonul Eryurek, Istanbul Technical Univ. (Turkey)
Hatun Cinkaya, Istanbul Technical Univ. (Turkey)
Murat Erdem, Marmara Univ. (Turkey)
Gokhan Bilir, Kafkas Üniv. (Turkey)

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